Hickson, J. R., Horsewill, S. J., McGuire, J., Wilson, C. , Sproules, S. and Farnaby, J. H. (2018) The semiquinone radical anion of 1,10-phenanthroline-5,6-dione: synthesis and rare earth coordination chemistry. Chemical Communications, 54(80), pp. 11284-11287. (doi: 10.1039/C8CC05591B) (PMID:30239538)
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Abstract
Reduction of 1,10-phenanthroline-5,6-dione (pd) with CoCpR2 resulted in the first molecular compounds of the pd˙− semi-quinone radical anion, [CoCpR2]+[pd]˙− (R = H, (1); R = Me4, (2)). Furthermore compounds 1 and 2 were reacted with [Y(hfac)3(thf)2] (hfac = 1,1,1-5,5,5-hexafluoroacetylacetonate) to synthesise the rare earth-transition metal heterometallic compounds, [CoCpR2]+[Y(hfac)3(N,N′-pd)]˙− (R = H, (3); R = Me4, (4)).
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Sproules, Dr Stephen and Hickson, Mr James Robert and Farnaby, Dr Joy and McGuire, Mr Jake and Horsewill, Mr Samuel and Wilson, Dr Claire |
| Authors: | Hickson, J. R., Horsewill, S. J., McGuire, J., Wilson, C., Sproules, S., and Farnaby, J. H. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Chemical Communications |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1359-7345 |
| ISSN (Online): | 1364-548X |
| Published Online: | 18 September 2018 |
| Copyright Holders: | Copyright © 2018 The Royal Society of Chemistry |
| First Published: | First published in Chemical Communications 54(80): 11284-11287 |
| Publisher Policy: | Reproduced under a Creative Commons License |
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