The semiquinone radical anion of 1,10-phenanthroline-5,6-dione: synthesis and rare earth coordination chemistry

Hickson, J. R., Horsewill, S. J., McGuire, J., Wilson, C. , Sproules, S. and Farnaby, J. H. (2018) The semiquinone radical anion of 1,10-phenanthroline-5,6-dione: synthesis and rare earth coordination chemistry. Chemical Communications, 54(80), pp. 11284-11287. (doi:10.1039/C8CC05591B) (PMID:30239538)

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Abstract

Reduction of 1,10-phenanthroline-5,6-dione (pd) with CoCpR2 resulted in the first molecular compounds of the pd˙− semi-quinone radical anion, [CoCpR2]+[pd]˙− (R = H, (1); R = Me4, (2)). Furthermore compounds 1 and 2 were reacted with [Y(hfac)3(thf)2] (hfac = 1,1,1-5,5,5-hexafluoroacetylacetonate) to synthesise the rare earth-transition metal heterometallic compounds, [CoCpR2]+[Y(hfac)3(N,N′-pd)]˙− (R = H, (3); R = Me4, (4)).

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Wilson, Dr Claire and Sproules, Dr Stephen and Farnaby, Dr Joy and Hickson, Mr James Robert and McGuire, Mr Jake and Horsewill, Mr Samuel
Authors: Hickson, J. R., Horsewill, S. J., McGuire, J., Wilson, C., Sproules, S., and Farnaby, J. H.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Chemical Communications
Publisher:Royal Society of Chemistry
ISSN:1359-7345
ISSN (Online):1364-548X
Published Online:18 September 2018
Copyright Holders:Copyright © 2018 The Royal Society of Chemistry
First Published:First published in Chemical Communications 54(80): 11284-11287
Publisher Policy:Reproduced under a Creative Commons License

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Project CodeAward NoProject NamePrincipal InvestigatorFunder's NameFunder RefLead Dept
701101EPSRC 2015 DTPMary Beth KneafseyEngineering and Physical Sciences Research Council (EPSRC)EP/M508056/1R&I - RESEARCH STRATEGY & INNOVATION