Heterometallic lanthanide-centred [NiII6LnIII] rings

Canaj, A. B. , Tzimopoulos, D., Kalofolias, D. A., Siczek, M., Lis, T., Murrie, M. and Milios, C. J. (2018) Heterometallic lanthanide-centred [NiII6LnIII] rings. Dalton Transactions, 47(37), pp. 12863-12867. (doi:10.1039/C8DT02855A) (PMID:30159573)

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Abstract

A [NiII6DyIII] heptanuclear complex featuring a rare six-membered {NiII6} metal ring surrounding the central Dy(III) ion is reported. Magnetic studies reveal single-molecule magnet behaviour for the complex under zero external dc field, while replacing the DyIII ion with ΥIII or GdIII ions allows for a comprehensive understanding of the magnetic behaviour.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Tsanai, Dr Angelos and Murrie, Professor Mark
Authors: Canaj, A. B., Tzimopoulos, D., Kalofolias, D. A., Siczek, M., Lis, T., Murrie, M., and Milios, C. J.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Dalton Transactions
Publisher:Royal Society of Chemistry
ISSN:1477-9226
ISSN (Online):1477-9234
Published Online:24 August 2018
Copyright Holders:Copyright © 2018 The Royal Society of Chemistry
First Published:First published in Dalton Transactions 47(37): 12863-12867
Publisher Policy:Reproduced in accordance with the publisher copyright policy

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