Collet, A., Craig, G. A., Heras Ojea, M. J., Bhaskaran, L., Wilson, C. , Hill, S. and Murrie, M. (2018) Slow magnetic relaxation in a {CoIICoIII2} complex containing a high magnetic anisotropy trigonal bipyramidal CoII centre. Dalton Transactions, 47(28), pp. 9237-9240. (doi: 10.1039/C8DT01997E) (PMID:29953164)
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Abstract
We report a trinuclear mixed-valence {CoIICoIII2} complex, where the CoII centre adopts a trigonal bipyramidal geometry, leading to a large easy-plane magnetic anisotropy and field-induced slow magnetic relaxation with a Raman-like relaxation process.
Item Type: | Articles |
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Additional Information: | A portion of this work was performed at the NHMFL, which is supported by the NSF (DMR-1157490 and DMR-1644779) and the State of Florida. SH also acknowledges the support of the NSF (DMR- 1610226). |
Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Wilson, Dr Claire and Craig, Dr Gavin and COLLET, Alexandra Foteini Tsampika and Murrie, Professor Mark and Heras Ojea, Miss Maria Jose |
Authors: | Collet, A., Craig, G. A., Heras Ojea, M. J., Bhaskaran, L., Wilson, C., Hill, S., and Murrie, M. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Dalton Transactions |
Publisher: | Royal Society of Chemistry |
ISSN: | 1477-9226 |
ISSN (Online): | 1477-9234 |
Published Online: | 18 June 2018 |
Copyright Holders: | Copyright © 2018 The Authors |
First Published: | First published in Dalton Transactions 47(28):9237-9240 |
Publisher Policy: | Reproduced under a Creative Commons License |
Data DOI: | 10.5525/gla.researchdata.618 |
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