Structural characterization and photochemical properties of mono-and bimetallic Cu-Mabiq complexes

Stark, H. S., Altmann, P. J., Sproules, S. and Hess, C. R. (2018) Structural characterization and photochemical properties of mono-and bimetallic Cu-Mabiq complexes. Inorganic Chemistry, 57(11), pp. 6401-6409. (doi:10.1021/acs.inorgchem.8b00471) (PMID:29767971)

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Abstract

A series of mono- and bimetallic copper-Mabiq complexes is described. One-electron reduction of the CuII and CuICuII complexes is ligand-centered, yielding the (Mabiq•) form of the macrocycle. Both bimetallic compounds are thus mixed-valent with respect to the metal ions. The influence of the outer copper ion on the redox, spectroscopic, and photochemical properties of the central ion was examined. The two metals ions interact weakly, such that the photoactivity of the central Cu-Mabiq unit is retained.

Item Type:Articles
Additional Information:2018-05-18 MSM Author confirmed published online and accepted dates are the same.
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Sproules, Dr Stephen
Authors: Stark, H. S., Altmann, P. J., Sproules, S., and Hess, C. R.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Inorganic Chemistry
Publisher:American Chemical Society
ISSN:0020-1669
ISSN (Online):1520-510X
Published Online:16 May 2018
Copyright Holders:Copyright © 2018 American Chemical Society
First Published:First published in Inorganic Chemistry 57(11):6401-6409
Publisher Policy:Reproduced in accordance with the copyright policy of the publisher

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