Purcell, J. W., Long, D.-L. , Lee, E. C. , Cronin, L. and Miras, H. N. (2018) Spontaneous formation of a chiral (Mo2O2S2)2+-based cluster driven by dimeric {Te2O6}-based templates. Dalton Transactions, 47(18), pp. 6283-6287. (doi: 10.1039/C8DT00832A) (PMID:29667663) (PMCID:PMC5944425)
|
Text
160905.pdf - Published Version Available under License Creative Commons Attribution. 1MB |
Abstract
Utilization of [Mo2S2O2(H2O)6]2+ and a tellurite anion led to the formation of three new clusters, 1–3, with unique structural features. The tellurite anion not only templated the formation of [(Mo2O2S2)4(TeO3)(OH)9]3− 1 and [(Mo2O2S2)12(TeO3)4(TeO4)2 (OH)18]10− 3, but also the in situ generation of two different types of dimeric {Te2O6} based moieties induced the spontaneous assembly of the chiral [(Mo2O2S2)10(TeO3)(Te2O6)2(OH)18]8− anionic cluster, 2.
Item Type: | Articles |
---|---|
Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Lee, Mr Eddy and Purcell, Mr Jamie and Moiras, Professor Haralampos and Long, Dr Deliang and Cronin, Professor Lee |
Authors: | Purcell, J. W., Long, D.-L., Lee, E. C., Cronin, L., and Miras, H. N. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Dalton Transactions |
Publisher: | Royal Society of Chemistry |
ISSN: | 1477-9226 |
ISSN (Online): | 1477-9234 |
Published Online: | 29 March 2018 |
Copyright Holders: | Copyright © 2018 The Royal Society of Chemistry |
First Published: | First published in Dalton Transactions 47(18):6283-6287 |
Publisher Policy: | Reproduced under a Creative Commons License |
University Staff: Request a correction | Enlighten Editors: Update this record