Skabara, P. J. , Arlin, J.-B. and Geerts, Y. H. (2013) Close encounters of the 3D kind - exploiting high dimensionality in molecular semiconductors. Advanced Materials, 25(13), pp. 1948-1954. (doi: 10.1002/adma.201200862) (PMID:23675597)
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Abstract
In this Research News article we discuss the significance of dimensionality on the charge‐transport properties of organic semiconductors. Dimensionality is defined in two ways: as a function of (i) the π‐conjugated framework within the molecular structure, and (ii) the degree and direction of intermolecular close‐contacts between molecules in the bulk. In terms of dimensionality, silicon is a good role model for organic semiconductors, since it demonstrates 3D architecture in the bulk through covalent bonding. Achieving this for organics is challenging and requires not only a 3D molecular structure, but also a network of intermolecular short contacts in three dimensions. This review identifies the limitations of low dimensional materials and summarizes the challenges faced in progressing towards fully 3D organic semiconductors.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Skabara, Professor Peter |
| Authors: | Skabara, P. J., Arlin, J.-B., and Geerts, Y. H. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Advanced Materials |
| Publisher: | Wiley |
| ISSN: | 0935-9648 |
| ISSN (Online): | 1521-4095 |
| Published Online: | 10 May 2012 |
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