Yang, Z. and Mai, K. (2010) Crystallization and melting behavior of β-nucleated isotactic polypropylene/polyamide 6 blends with maleic anhydride grafted polyethylene-vinyl acetate as a compatibilizer. Thermochimica Acta, 511(1-2), pp. 152-158. (doi: 10.1016/j.tca.2010.08.007)
Full text not currently available from Enlighten.
Abstract
β-Nucleated isotactic polypropylene (β-iPP) blend with maleic anhydride grafted polyethylene-vinyl acetate (EVA-g-MA) and β-iPP/polyamide (PA) 6 blend, as well as its compatibilized version with EVA-g-MA as a compatibilizer were prepared with an internal mixer. Analysis from differential scanning calorimeter (DSC) and wide angle X-ray diffraction (WAXD) indicates that the addition of EVA-g-MA into β-nucleated iPP decreases the crystallization temperature (Tcp) of PP, but it has no pronounced influence on the β-crystal content for β-nucleated iPP. For β-nucleated iPP/PA6 blends, PA6 obviously decreases the β-crystal content. However, the addition of EVA-g-MA is quite benefit for the formation of β-crystal in β-nucleated iPP/PA6 blends and the β-crystal content increases with increasing EVA-g-MA content. It is suggested that the nucleating agent mainly disperses in the PA6 phase and/or the interface between iPP and PA6 in iPP/PA6 blend, which was proved by etching the blends with sulfuric acid and experimental facts from SEM.
Item Type: | Articles |
---|---|
Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Yang, Dr Zhugen |
Authors: | Yang, Z., and Mai, K. |
College/School: | College of Science and Engineering > School of Engineering > Biomedical Engineering |
Journal Name: | Thermochimica Acta |
Publisher: | Elsevier |
ISSN: | 0040-6031 |
ISSN (Online): | 1872-762X |
Published Online: | 13 August 2010 |
University Staff: Request a correction | Enlighten Editors: Update this record