Direct solid phase microextraction combined with gas chromatography – mass spectrometry for the determination of biogenic amines in wine

Papageorgiou, M., Lambropoulou, D., Morrison, C. , Namieśnik, J. and Płotka-Wasylka, J. (2018) Direct solid phase microextraction combined with gas chromatography – mass spectrometry for the determination of biogenic amines in wine. Talanta, 183, pp. 276-282. (doi: 10.1016/j.talanta.2018.02.006) (PMID:29567176)

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Abstract

A direct method based on immersion solid phase microextraction (DI-SPME) gas chromatography mass-spectrometry (GC-MS) was optimized and validated for the determination of 16 biogenic amines in Polish wines. In the analysis two internal standards were used: 1,7-diaminoheptane and bis-3-aminopropylamine. The method allows for simultaneous extraction and derivatization, providing a simple and fast mode of extraction and enrichment. Different parameters which affect the extraction procedure were studied and optimized including ionic strength (0–25%), fiber materials (PDMS/DVB, PDMS/DVD+OC, Polyacrylate, Carboxen/PDMS and DVB/CAR/PDMS) and timings of the extraction, derivatization and desorption processes. Validation studies confirmed the linearity, sensitivity, precision and accuracy of the method. The method was successfully applied to the analysis of 44 wine samples originating from several regions of Poland and 3 wine samples from other countries. Analysis showed that many of the samples contained all examined biogenic amines. The method, assessed using an Eco-Scale tool with satisfactory results, was found to be green in terms of hazardous chemicals and solvents usage, energy consumption and production of waste. Therefore the proposed method can be safely used in the wine industry for routine analysis of BAs in wine samples with a minimal detrimental impact on human health and the environment.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Morrison, Dr Calum
Authors: Papageorgiou, M., Lambropoulou, D., Morrison, C., Namieśnik, J., and Płotka-Wasylka, J.
College/School:College of Medical Veterinary and Life Sciences > School of Medicine, Dentistry & Nursing
Journal Name:Talanta
Publisher:Elsevier
ISSN:0039-9140
ISSN (Online):1873-3573
Published Online:12 February 2018
Copyright Holders:Copyright © 2018 Elsevier B.V.
First Published:First published in Talanta 183: 276-282
Publisher Policy:Reproduced in accordance with the copyright policy of the publisher

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