Kakaroni, F. E., Collet, A., Sakellari, E., Tzimopoulos, D., Siczek, M., Lis, T., Murrie, M. and Milios, C. J. (2018) Constructing CrIII-centered heterometallic complexes: [NiII6CrIII] and [CoII6CrIII] wheels. Dalton Transactions, 47(1), pp. 58-61. (doi: 10.1039/C7DT04043A)
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Abstract
The solvothermal reaction between Cr(acac)3, MCl2.6H2O (M= Ni, Co) and 2-hydroxy-4-methyl-6-phenyl-pyridine-3-amidoxime (H2L), under basic conditions, led to the synthesis of the heterometallic heptanuclear clusters [MII6Cr(HLzw)6(HL)6].3Cl (M= Ni, 1; Co, 2), with the nickel analogue displaying an S= 9/2 spin ground-state.
| Item Type: | Articles |
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| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Collet, Miss Alexandra Fotei and Murrie, Professor Mark |
| Authors: | Kakaroni, F. E., Collet, A., Sakellari, E., Tzimopoulos, D., Siczek, M., Lis, T., Murrie, M., and Milios, C. J. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Dalton Transactions |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1477-9226 |
| ISSN (Online): | 1477-9234 |
| Published Online: | 17 November 2017 |
| Copyright Holders: | Copyright © 2017 The Royal Society of Chemistry |
| First Published: | First published in Dalton Transactions 47(1):58-61 |
| Publisher Policy: | Reproduced in accordance with the publisher copyright policy |
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