Docherty, F.T., Craven, A.J., and McComb, D.W. (1999) ELNES investigations of the structure and electronic properties of chromium spinels. In: Institute of Physics; Electron Microscopy and Analysis Group, August 1999, Sheffield.
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A series of spinels have been studied to investigate the influence of the occupation of d orbitals on the energy loss near edge structure (ELNES). In this paper the oxygen K edges from a variety of chromium spinels and magnesium aluminate are presented. Extra fine structure is observed from compounds containing transition metals with partially filled d orbitals. This is assigned to transitions to states created by hybridisation of the oxygen 2p and transition metal 3d orbitals at the bottom of the conduction band.
|Item Type:||Conference Proceedings|
|Glasgow Author(s) Enlighten ID:||Craven, Prof Alan|
|Authors:||Docherty, F.T., Craven, A.J., and McComb, D.W.|
|Subjects:||Q Science > QC Physics|
|College/School:||College of Science and Engineering > School of Physics and Astronomy|
|Journal Name:||Electron Microscopy and Analysis 1999|