Total CCl4 guest alignment in a quasiracemic clathrate closely related to Dianin's compound

Frampton, C. S., Gall, J. H. and MacNicol, D. D. (2017) Total CCl4 guest alignment in a quasiracemic clathrate closely related to Dianin's compound. CrystEngComm, 19(38), pp. 5703-5706. (doi: 10.1039/c7ce01275f)

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Abstract

Single crystal X-ray analysis at 100 K reveals that in the trigonal CCl4quasiracemic clathrate, space group R3, formed from host components S-(−)-Dianin's compound and its (+)-2R,4R 2-nor methyl analogue there is an unprecedented complete ordering of a C–Cl bond of the guest with respect to the c-axial direction. In this clathrate and that formed from the (+)-2R,4R and (+)-2R,4S epimers the participation of an unexpected host conformation is reported for the first time.

Item Type:Articles
Additional Information:Financial support from the Malaysia HIR MOHE, Grant No. F000009-2100.
Keywords:General materials science, general chemistry, condensed matter physics.
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Gall, Mr James and MacNicol, Dr David
Authors: Frampton, C. S., Gall, J. H., and MacNicol, D. D.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:CrystEngComm
Publisher:Royal Society of Chemistry (RSC)
ISSN:1466-8033
ISSN (Online):1466-8033
Published Online:07 August 2017

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