Keat, R., Rycroft, D.S., Miller, V.R., Schmulbach, C.D. and Shaw, R.A. (1981) The structures of pentaphenylcyclotriphosphazatriene-derivatives; a 31P n.m.r. investigation. Phosphorus and Sulfur and the Related Elements, 10(1), pp. 121-122. (doi: 10.1080/03086648108078279)
Full text not currently available from Enlighten.
Abstract
A 31P n.m.r. study of a compound previously thought to be a hydroxyphosphazene, N3P3(OH)Ph5, shows that it is present in solution as an oxophosphazane, N3HP3(O)Ph5. Its condensation product, (N3P3Ph5)2O, gives a 31P spectrum which can be analysed as an A2BB'A'2 spin system, confirming that it has an oxygen-bridged phosphazene structure.
Item Type: | Articles |
---|---|
Keywords: | Phosphorus chemistry, NMR spectroscopy. |
Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Rycroft, Dr David |
Authors: | Keat, R., Rycroft, D.S., Miller, V.R., Schmulbach, C.D., and Shaw, R.A. |
Subjects: | Q Science > QD Chemistry |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Phosphorus and Sulfur and the Related Elements |
Publisher: | Gordon and Breach Science |
ISSN: | 0308-664X |
University Staff: Request a correction | Enlighten Editors: Update this record