The sign of the lithium—carbon nuclear spin coupling constant in methyllithium tetramer

McFarlane, W. and Rycroft, D. S. (1974) The sign of the lithium—carbon nuclear spin coupling constant in methyllithium tetramer. Journal of Organometallic Chemistry, 64(3), pp. 303-305. (doi: 10.1016/S0022-328X(00)92176-4)

Abstract

Heteronuclear magnetic double resonance experiments are used to show that ¹J(⁷Li—¹³C) is positive in methyllithium tetramer. This is consistent with dominance of the coupling mechanism by the Fermi contact interaction.

• Item Type: Articles
• Keywords: Organometallic chemistry, NMR spectroscopy, multiple resonance.
• Status: Published
• Refereed: Yes
• Glasgow Author(s) Enlighten ID: Rycroft, Dr David
• Authors: McFarlane, W., and Rycroft, D. S.
• Subjects: Q Science > QD Chemistry
• College/School: College of Science and Engineering > School of Chemistry
• Journal Name: Journal of Organometallic Chemistry
• Publisher: Elsevier
• ISSN: 0022-328X
• ISSN (Online): 1872-8561