An eco-friendly dyeing of woolen yarn by Terminalia chebula extract with evaluations of kinetic and adsorption characteristics

Shabbir, M., Rather, L. J., Shahid-ul-Islam, , Bukhari, M. N., Shahid, M. , Ali Khan, M. and Mohammad, F. (2016) An eco-friendly dyeing of woolen yarn by Terminalia chebula extract with evaluations of kinetic and adsorption characteristics. Journal of Advanced Research, 7(3), pp. 473-482. (doi: 10.1016/j.jare.2016.03.006) (PMID:27222752) (PMCID:PMC4856821)

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Abstract

In the present study Terminalia chebula was used as an eco-friendly natural colorant for sustainable textile coloration of woolen yarn with primary emphasis on thermodynamic and kinetic adsorption aspects of dyeing processes. Polyphenols and ellagitannins are the main coloring components of the dye extract. Assessment of the effect of pH on dye adsorption showed an increase in adsorption capacity with decreasing pH. Effect of temperature on dye adsorption showed 80 °C as optimum temperature for wool dyeing with T. chebula dye extract. Two kinetic equations, namely pseudo first-order and pseudo second-order equations, were employed to investigate the adsorption rates. Pseudo second-order model provided the best fit (R2 = 0.9908) to the experimental data. The equilibrium adsorption data were fitted by Freundlich and Langmuir isotherm models. The adsorption behavior accorded well (R2 = 0.9937) with Langmuir isotherm model. Variety of eco-friendly and sustainable shades were developed in combination with small amount of metallic mordants and assessed in terms of colorimetric (CIEL∗a∗b∗ and K/S) properties measured using spectrophotometer under D65 illuminant (10° standard observer). The fastness properties of dyed woolen yarn against light, washing, dry and wet rubbing were also evaluated.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Shahid, Dr Mohammad
Authors: Shabbir, M., Rather, L. J., Shahid-ul-Islam, , Bukhari, M. N., Shahid, M., Ali Khan, M., and Mohammad, F.
College/School:College of Arts & Humanities > School of Culture and Creative Arts > History of Art
Journal Name:Journal of Advanced Research
Publisher:Elsevier
ISSN:2090-1232
ISSN (Online):2090-1224
Published Online:29 March 2016
Copyright Holders:Copyright © 2016 Elsevier B.V.
First Published:First published in Journal of Advanced Research 7(3): 473-482
Publisher Policy:Reproduced under a Creative Commons License

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