McGhee, L., Rycroft, D. S. and Winfield, J. M. (1987) Oxidation of molecular bromine by uranium hexafluoride in acetonitrile. Preparation and properties of hexafluorouranates(V) containing positive bromine. Journal of Fluorine Chemistry, 36(3), pp. 351-359. (doi: 10.1016/S0022-1139(00)82077-1)
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Abstract
Molecular bromine is oxidized by uranium hexafluoride in acetonitrile at ambient temperature. The product is formulated on the basis of its spectra, and its brominating and oxidizing abilities as [Br(C<sub>6</sub>H<sub>9</sub>N<sub>3</sub>)][UF<sub>6</sub>] in which bromine is bound to an acetonitrile trimer containing C=N bonds.
Item Type: | Articles |
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Keywords: | NMR spectroscopy. |
Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Winfield, Professor John and Rycroft, Dr David |
Authors: | McGhee, L., Rycroft, D. S., and Winfield, J. M. |
Subjects: | Q Science > QD Chemistry |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Journal of Fluorine Chemistry |
Publisher: | Elsevier |
ISSN: | 0022-1139 |
ISSN (Online): | 1873-3328 |
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