Oxidation of molecular bromine by uranium hexafluoride in acetonitrile. Preparation and properties of hexafluorouranates(V) containing positive bromine

McGhee, L., Rycroft, D. S. and Winfield, J. M. (1987) Oxidation of molecular bromine by uranium hexafluoride in acetonitrile. Preparation and properties of hexafluorouranates(V) containing positive bromine. Journal of Fluorine Chemistry, 36(3), pp. 351-359. (doi:10.1016/S0022-1139(00)82077-1)

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Abstract

Molecular bromine is oxidized by uranium hexafluoride in acetonitrile at ambient temperature. The product is formulated on the basis of its spectra, and its brominating and oxidizing abilities as [Br(C6H9N3)][UF6] in which bromine is bound to an acetonitrile trimer containing C=N bonds.

Item Type:Articles
Keywords:NMR spectroscopy.
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Winfield, Professor John and Rycroft, Dr David
Authors: McGhee, L., Rycroft, D. S., and Winfield, J. M.
Subjects:Q Science > QD Chemistry
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Journal of Fluorine Chemistry
Publisher:Elsevier
ISSN:0022-1139
ISSN (Online):1873-3328

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