Docherty, J. B., Rycroft, D. S., Sharp, D. W.A. and Webb, G. A. (1979) Restricted rotation and preferred conformations in tris(pentafluorophenyl)phosphine platinum(II) complexes; the mechanism of helicity reversal in a co-ordinated triarylphosphine. Journal of the Chemical Society: Chemical Communications, 1979(7), pp. 336-337. (doi: 10.1039/C39790000336)
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Abstract
Variable temperature 19F and 31P n.m.r. studies of some tris(pentafluorophenyl)phosphine platinum complexes show restricted rotation at low temperatures about the Pt–P and C(1)–P bonds with a preferred conformation in which none of the C(1)–P bonds lie in the platinum co-ordination plane; the mechanism of helicity reversal of the propeller-shaped ligand is a two-ring flip.
Item Type: | Articles |
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Keywords: | Phosphorus chemistry, NMR spectroscopy. |
Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Rycroft, Dr David |
Authors: | Docherty, J. B., Rycroft, D. S., Sharp, D. W.A., and Webb, G. A. |
Subjects: | Q Science > QD Chemistry |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Journal of the Chemical Society: Chemical Communications |
Publisher: | Royal Society of Chemistry |
ISSN: | 0022-4936 |
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