Chatterjea, J. N., Lal, S., Jha, U., Rycroft, D. S. and Carnduff, J. (1979) Acylation of 2-alkylnaphtho[2,1-b]furan. Journal of Chemical Research(11), (S) 356; (M) 4075-4085.
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Abstract
Formylation of certain 2-alkylnaphtho[2,1-b]furans is shown to occur in the naphthalene rather than the furan ring. Acetylation gives a mixture of isomers. Hydrolysis of the 1-(acetoxyethylidene)furan-2-one does not give the 2-methyl-1-carboxylic acid. In contrast in the 2-methylnaphtho[1,2-b]furan series, the formylation-oxidation route and the acetoxyethylidenefuranone rearrangement both give the 2-methyl-3-carboxylic acid.
| Item Type: | Articles |
|---|---|
| Keywords: | NMR spectroscopy. |
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Rycroft, Dr David |
| Authors: | Chatterjea, J. N., Lal, S., Jha, U., Rycroft, D. S., and Carnduff, J. |
| Subjects: | Q Science > QD Chemistry |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Journal of Chemical Research |
| Publisher: | The Chemical Society |
| ISSN: | 0308-2342 |
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