Alkylimidotungsten(VI) fluorides

Chambers, O. R., Harman, M. E., Rycroft, D. S., Sharp, D. W.A. and Winfield, J. M. (1977) Alkylimidotungsten(VI) fluorides. Journal of Chemical Research(6), (S) 150-151-(M) 1849-1876.

Full text not currently available from Enlighten.

Abstract

Although a number of transition-metal compounds containing terminal alkylimido-ligands are known, 1H—14N spin—spin coupling has apparently not been observed in their n.m.r. spectra. We report the preparation and characterisation of several alkylimido-derivatives of tungsten hexafluoride in which spin—spin coupling interactions involving 14N are observed. The observation of n.m.r. parameters involving 14N enables structural assignments to be made.

Item Type:Articles
Keywords:NMR spectroscopy.
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Winfield, Professor John and Rycroft, Dr David
Authors: Chambers, O. R., Harman, M. E., Rycroft, D. S., Sharp, D. W.A., and Winfield, J. M.
Subjects:Q Science > QD Chemistry
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Journal of Chemical Research
Publisher:The Chemical Society
ISSN:0308-2342

University Staff: Request a correction | Enlighten Editors: Update this record