Manjakkal, L. , Zaraska, K., Cvejin, K., Kulawik, J. and Szwagierczak, D. (2016) Potentiometric RuO2–Ta2O5 pH sensors fabricated using thick film and LTCC technologies. Talanta, 147, pp. 233-240. (doi: 10.1016/j.talanta.2015.09.069) (PMID:26592601)
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Abstract
The paper reports on the preparation, properties and application of potentiometric pH sensors with thick film RuO2–Ta2O5 sensing electrode and Ag/AgCl/KCl reference electrode screen printed on an alumina substrate. Furthermore, it presents fabrication procedure and characterization of a new miniaturized pH sensor on LTCC (low temperature cofired ceramics) substrate, destined for wireless monitoring. The crystal structure, phase and elemental composition, and microstructure of the films were investigated by X-ray diffractometry, Raman spectroscopy, scanning electron microscopy and energy dispersive spectroscopy. Potentiometric characterization was performed in a wide pH range of 2–12 for different storage conditions and pH loops. The advantages of the proposed thick film pH sensors are: (a) low cost and easy fabrication, (b) excellent sensitivity close to the Nernstian response (56 mV/pH) in the wide pH range, (c) fast response, (d) long lifetime, (e) good reproducibility, (f) low hysteresis and drift effects, and (g) low cross-sensitivity towards Li+, Na+ and K+ as interfering ions. The applicability of the sensors for pH measurement of river, tap and distilled water, and some drinks was also tested.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Manjakkal, Dr Libu |
Authors: | Manjakkal, L., Zaraska, K., Cvejin, K., Kulawik, J., and Szwagierczak, D. |
College/School: | College of Science and Engineering > School of Engineering > Electronics and Nanoscale Engineering |
Journal Name: | Talanta |
Publisher: | Elsevier |
ISSN: | 0039-9140 |
ISSN (Online): | 1873-3573 |
Published Online: | 30 September 2015 |
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