Rycroft, D. S., Connolly, J. D., Huneck, S. and Himmelreich, U. (1995) Revised structure of haemoventosin. Zeitschrift für Naturforschung B - A Journal of Chemical Sciences, 50(10), pp. 1557-1563. (doi:10.1515/znb-1995-1021)
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Abstract
The structure of the lichen pigment haemoventosin has been revised to 3,4,6,9-tetrahydro-5,10-dihydroxy-7-methoxy-3S-methyl-1,6,9-trioxo-1H-naphtho-[2,3-c]pyran (3), mainly on the basis of long-range δC/δH correlations observed in 2D HMBC NMR experiments and long-range δH/δD isotope effects observed in partial deuteriation experiments with 10-O-acetylhaemoventosin; ortho- and para-quinonoid structures were distinguished by means of the transacetylation inferred in the sodium dithionite reduction of 10-O-acetylhaemoventosin.
| Item Type: | Articles |
|---|---|
| Keywords: | Naphthoquinone, Ophioparma ventosa, lichen, NMR spectroscopy, long-range isotope effects. |
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Connolly, Professor Joseph and Rycroft, Dr David |
| Authors: | Rycroft, D. S., Connolly, J. D., Huneck, S., and Himmelreich, U. |
| Subjects: | Q Science > QD Chemistry Q Science > QK Botany |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Zeitschrift für Naturforschung B - A Journal of Chemical Sciences |
| Publisher: | Verlag der Zeitschrift für Naturforschung |
| ISSN: | 0932-0776 |
| ISSN (Online): | 1865-7117 |
| Copyright Holders: | Copyright © 1995 Verlag der Zeitschrift für Naturforschung |
| First Published: | First published in Zeitschrift für Naturforschung B - A Journal of Chemical Sciences 50(10): 1557-1563 |
| Publisher Policy: | Reproduced under a Creative Commons License |
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