Barron, L. D. (1977) Raman optical activity of camphor and related molecules. Journal of the Chemical Society: Perkin Transactions 2, 1977(8), pp. 1074-1079. (doi: 10.1039/P29770001074)
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Abstract
Raman circular intensity differential spectra between 80 and 2 000 cm–1 of (+)-camphor, (+)-3-bromocamphor, (–)-3-bromocamphor-9-sulphonic acid, (+)-3-chlorocamphor, (–)-bornan-2-endo-ol, (–)-bornan-2-exo-ol, and (+)-3-methylcyclohexanone are presented. Several correlations are pointed out, including large conservative couplets at ca. 500 cm–1 that might originate in in-plane and out-of-plane carbonyl deformations. It is demonstrated that the conservative couplets which often dominate Raman optical activity spectra originate in coupling of two vibrational modes of appropriate symmetry through a chiral distortion of the molecular framework.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Barron, Professor Laurence |
Authors: | Barron, L. D. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Journal of the Chemical Society: Perkin Transactions 2 |
Publisher: | Royal Society of Chemistry |
ISSN: | 1472-779X |
ISSN (Online): | 1364-5471 |
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