Vibrational Raman optical activity of cyclodextrins

Barron, L. D., Gargaro, A. R., Wen, Z. Q., MacNicol, D. D. and Butters, C. (1990) Vibrational Raman optical activity of cyclodextrins. Tetrahedron: Asymmetry, 1(8), pp. 513-516. (doi:10.1016/S0957-4166(00)80537-6)

Full text not currently available from Enlighten.

Abstract

Vibrational Raman optical activity spectra of aqueous solutions of α−, β− and γ-D-cyclodextrin in the range 700–1500 cm−1 are reported. As well as showing features characteristics of D-glucose, the ROA spectra all show remarkably intense features between 890 and 960 cm−1 originating in coupled C(1)-H deformations and glycosidic C-O stretches delocalized around the cyclodextrin ring and which reflect the stereochemistry of the glycosidic links.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:MacNicol, Dr David and Barron, Professor Laurence
Authors: Barron, L. D., Gargaro, A. R., Wen, Z. Q., MacNicol, D. D., and Butters, C.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Tetrahedron: Asymmetry
Publisher:Elsevier
ISSN:0957-4166
ISSN (Online):1362-511X

University Staff: Request a correction | Enlighten Editors: Update this record