Determination of absolute configurations from vibrational raman optical activity: trans-2,3-dimethylthiirane

Polavarapu, P. L., Pickard, S. T., Smith, H. E., Black, T. M., Barron, L. D. and Hecht, L. (1993) Determination of absolute configurations from vibrational raman optical activity: trans-2,3-dimethylthiirane. Talanta, 40(4), pp. 545-549. (doi:10.1016/0039-9140(93)80015-J) (PMID:18965664)

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Abstract

Experimental and theoretical vibrational Raman optical activity (VROA) spectra of (2R,3R)-2,3-dimethylthiirane in the 200–1500 cm−1 region are presented. The level of agreement obtained for the observed and predicted VROA signs suggests that the absolute configurations of chiral molecules can be determined confidently using VROA.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Hecht, Dr Lutz and Barron, Professor Laurence
Authors: Polavarapu, P. L., Pickard, S. T., Smith, H. E., Black, T. M., Barron, L. D., and Hecht, L.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Talanta
Publisher:Pergamon Press Ltd
ISSN:0039-9140
ISSN (Online):1873-3573

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