Gargaro, A.R., Barron, L.D. and Hecht, L. (1993) Vibrational Raman optical activity of simple amino acids. Journal of Raman Spectroscopy, 24(2), pp. 91-96. (doi: 10.1002/jrs.1250240206)
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Abstract
The vibrational Raman optical activity (ROA) spectra of the simple amino acids L-serine, L-cysteine, L-valine, L-threonine and L-isoleucine in aqueous solution between 600 and 1600 cm−1 measured in backscattering are presented and discussed. Complete vibrational assignments are suggested for serine and cysteine and limited assignments for the others. Bands originating in Cα*H deformations and the symmetric CO2− stretch appear to provide the best signatures for stereochemical studies. The results show that ROA provides a new perspective on amino acid conformation in aqueous solution.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Hecht, Dr Lutz and Barron, Professor Laurence |
| Authors: | Gargaro, A.R., Barron, L.D., and Hecht, L. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Journal of Raman Spectroscopy |
| Publisher: | Wiley |
| ISSN: | 0377-0486 |
| ISSN (Online): | 1097-4555 |
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