Low-wavenumber vibrational Raman optical activity of carbohydrates

Bell, A. F., Hecht, L. and Barron, L. D. (1993) Low-wavenumber vibrational Raman optical activity of carbohydrates. Journal of Raman Spectroscopy, 24(9), pp. 633-635. (doi:10.1002/jrs.1250240913)

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Abstract

A high optical density holographic notch filter in combination with a single-grating spectrograph was used to increase the spectral range for backscattered Raman optical activity (ROA) measurements of biological molecules in aqueous solution towards lower wavenumber. ROA spectra of D-galactose, D-maltose and laminarin starting at ca. 350 cm−1 are presented as first examples. An ROA couplet observed at 427 ± 10 cm−1 in the spectra of D-maltose, D-cellobiose and laminarin appears to reflect the configuration of glycosidic links in di- and poly-saccharides.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Hecht, Dr Lutz and Barron, Professor Laurence
Authors: Bell, A. F., Hecht, L., and Barron, L. D.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Journal of Raman Spectroscopy
Publisher:Wiley
ISSN:0377-0486
ISSN (Online):1097-4555

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