Adams, D. J. , Tavener, S. J. and Clark, J. H. (1998) Reactions of silver(I) trifluoromethanethiolate with halotrimethylsilanes: in situ generation of trimethylsilyl trifluoromethyl sulfide. Journal of Fluorine Chemistry, 90(1), pp. 87-91. (doi: 10.1016/S0022-1139(98)00163-8)
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Abstract
Silver(I) trifluoromethanethiolate reacts with halotrimethylsilanes to produce silver halide, fluorotrimethylsilane and an oligomeric species of formula (CS)3 (SCF3)2. Variable temperature 19F NMR spectroscopy reveals that the reaction proceeds via trimethylsilyl trifluoromethyl sulfide (Me3SiSCF3), which rapidly decomposes on warming. This acts as a source of nucleophilic trifluoromethanethiolate, reacting with highly activated haloaromatics to produce trifluoromethyl aryl sulfides.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Adams, Dave |
Authors: | Adams, D. J., Tavener, S. J., and Clark, J. H. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Journal of Fluorine Chemistry |
Publisher: | Elsevier |
ISSN: | 0022-1139 |
ISSN (Online): | 1873-3328 |
Published Online: | 02 March 1999 |
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