Synthesis and coordination chemistry of perfluoroalkyl-derivatised triarylphosphites

Adams, D. J. , Gudmunsen, D., Fawcett, J., Hope, E. G. and Stuart, A. M. (2002) Synthesis and coordination chemistry of perfluoroalkyl-derivatised triarylphosphites. Tetrahedron, 58(20), pp. 3827-3834. (doi:10.1016/S0040-4020(02)00208-9)

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Abstract

A series of ortho-, meta- and para-perfluoroalkyl-substituted triaryl phosphites have been prepared and their coordination chemistry investigated. Spectroscopic and structural data for the metal complexes indicate that, even with the additional oxygen spacer unit, complete electronic insulation of the phosphorus(III) centres is not achieved.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Adams, Dave
Authors: Adams, D. J., Gudmunsen, D., Fawcett, J., Hope, E. G., and Stuart, A. M.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Tetrahedron
Publisher:Elsevier
ISSN:0040-4020
ISSN (Online):1464-5416
Published Online:18 March 2002

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