Asymmetric hydrogenation with perfluoroalkylated monodentate phosphorus(iii) ligands in supercritical CO2 and CH2Cl2

Adams, D. J. , Chen, W., Hope, E. G., Lange, S., Stuart, A. M., West, A. and Xiao, J. (2003) Asymmetric hydrogenation with perfluoroalkylated monodentate phosphorus(iii) ligands in supercritical CO2 and CH2Cl2. Green Chemistry, 5(2), pp. 118-122. (doi:10.1039/B212313B)

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Abstract

Four chiral perfluoroalkylated monodentate phosphorus(III) ligands have been prepared and characterised. These ligands have been evaluated in the rhodium-catalysed asymmetric hydrogenation of dimethyl itaconate in both dichloromethane and supercritical CO2 (scCO2) and compared with the parent, non-perfluoroalkylated, catalyst systems.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Adams, Dave
Authors: Adams, D. J., Chen, W., Hope, E. G., Lange, S., Stuart, A. M., West, A., and Xiao, J.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Green Chemistry
Publisher:Royal Society of Chemistry
ISSN:1463-9262
ISSN (Online):1463-9270
Published Online:27 March 2003

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