Synthesis and characterisation of trisarylphosphine selenides: further insight into the effect of fluoroalkylation on the electronic properties of trisarylphosphines

Adams, D. J. , Bennett, J. A., Duncan, D., Hope, E. G., Hopewell, J., Stuart, A. M. and West, A. J. (2007) Synthesis and characterisation of trisarylphosphine selenides: further insight into the effect of fluoroalkylation on the electronic properties of trisarylphosphines. Polyhedron, 26(7), pp. 1505-1513. (doi:10.1016/j.poly.2006.11.025)

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Abstract

Variations in the magnitude of the 1JSeP coupling constants for a range of phosphorus(V) selenides allow the efficiency of different spacer groups at insulating the phosphorus centre in triarylphosphines from highly electron-withdrawing perfluoroalkyl groups to be established.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Adams, Dave
Authors: Adams, D. J., Bennett, J. A., Duncan, D., Hope, E. G., Hopewell, J., Stuart, A. M., and West, A. J.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Polyhedron
Publisher:Elsevier
ISSN:0277-5387
ISSN (Online):0277-5387
Published Online:23 November 2006

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