Dawson, R., Ratvijitvech, T., Corker, M., Laybourn, A., Khimyak, Y. Z., Cooper, A. I. and Adams, D. J. (2015) Microporous copolymers for increased gas selectivity. Polymer Chemistry, 3(8), pp. 2034-2038. (doi: 10.1039/C2PY20136D)
Full text not currently available from Enlighten.
Abstract
Microporous organic polymers have been synthesised from aniline using Friedel–Crafts alkylation. Networks synthesised solely from aniline were non-porous to nitrogen. However, co-polymerisation with benzene resulted in networks with apparent Brunauaer-Emmett-Teller (BET) surface areas up to 1100 m2 g−1. Increased aniline content in the hyper-crosslinked networks led to improved CO2/N2 selectivity, suggesting a strategy for the design of materials for post-combustion carbon capture.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Adams, Dave |
| Authors: | Dawson, R., Ratvijitvech, T., Corker, M., Laybourn, A., Khimyak, Y. Z., Cooper, A. I., and Adams, D. J. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Polymer Chemistry |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1759-9954 |
| ISSN (Online): | 1759-9962 |
| Published Online: | 15 May 2012 |
University Staff: Request a correction | Enlighten Editors: Update this record
Deposit and Record Details
Deposit and Record Details