Laybourn, A., Dawson, R., Clowes, R., Hasell, T., Cooper, A. I., Khimyak, Y. Z. and Adams, D. J. (2014) Network formation mechanisms in conjugated microporous polymers. Polymer Chemistry, 5(21), pp. 6325-6333. (doi: 10.1039/C4PY00647J)
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Abstract
We discuss in detail the mechanism of formation of a highly microporous polymer, CMP-1, formed mainly via Sonogashira–Hagihara coupling. We demonstrate how the microporosity evolves with time, and discuss the importance of alkyne homo-coupling on the microporosity.
| Item Type: | Articles |
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| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Adams, Dave |
| Authors: | Laybourn, A., Dawson, R., Clowes, R., Hasell, T., Cooper, A. I., Khimyak, Y. Z., and Adams, D. J. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Polymer Chemistry |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1759-9954 |
| ISSN (Online): | 1759-9962 |
| Published Online: | 21 July 2014 |
| Copyright Holders: | Copyright © 2014 The Royal Society of Chemistry |
| First Published: | First published in Polymer Chemistry 5(21): 6325-6333 |
| Publisher Policy: | reproduced under a Creative Commons license |
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