Trinuclear {M1}CN{M2}2 complexes (M1= CrIII, FeIII, CoIII; M2= CuII, NiII, MnII). Are single molecule magnets predictable?

Atanasov, M., Busche, C., Comba, P., El Hallak, F., Martin, B., Rajaraman, G., van Slageren, J. and Wadepohl, H. (2008) Trinuclear {M1}CN{M2}2 complexes (M1= CrIII, FeIII, CoIII; M2= CuII, NiII, MnII). Are single molecule magnets predictable? Inorganic Chemistry, 47(18), pp. 8112-8125. (doi:10.1021/ic800556c) (PMID:18714990)

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Abstract

The structures and magnetic properties of a series of hexacyanometalate-based trinuclear complexes with linear or bent geometries is analyzed with an orbital-dependent extended Heisenberg Hamiltonian. The absence of SMM behavior is shown to be due to the large angular distortions of the hexacyanoferrate centers.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Busche, Dr Christoph
Authors: Atanasov, M., Busche, C., Comba, P., El Hallak, F., Martin, B., Rajaraman, G., van Slageren, J., and Wadepohl, H.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Inorganic Chemistry
Publisher:American Chemical Society
ISSN:0020-1669
ISSN (Online):1520-510X
Published Online:21 August 2008

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