Synthesis and structures of potassium bisdithiocarbamate salts

Cook, D.A., Coles, S.J., Hursthouse, M.B. and Price, D.J. (2003) Synthesis and structures of potassium bisdithiocarbamate salts. Zeitschrift für Anorganische und Allgemeine Chemie, 629(2), pp. 192-194. (doi:10.1002/zaac.200390030)

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Abstract

Two structurally related dipotassium bisdithiocarbamate salts: K2[(S2CNRCH2)2](EtOH)2; R = Me, i-Pr, were synthesised from the corresponding diamines. X-ray structure determinations were performed on single crystals grown from ethanolic solutions. The different alkyl substituents have a profound affect upon the solid-state structures, with the methyl derivative possessing a complex a 3-D network and the isopropyl derivative a 2-D lamellar structure.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Price, Dr Daniel
Authors: Cook, D.A., Coles, S.J., Hursthouse, M.B., and Price, D.J.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Zeitschrift für Anorganische und Allgemeine Chemie
ISSN:0044-2313
ISSN (Online):1521-3749
Published Online:29 January 2003

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