1,4-diazoniabicyclo[2.2.2]octane aquabis(oxalato-kappa(2)O,O')copper(II) dihydrate

Keene, T.D., Hursthouse, M.B. and Price, D.J. (2004) 1,4-diazoniabicyclo[2.2.2]octane aquabis(oxalato-kappa(2)O,O')copper(II) dihydrate. Acta Crystallographica. Section E: Structure Reports Online, 60(4), M378-M380. (doi: 10.1107/S1600536804005033)

Abstract

The title compound, (C6H14N2)[Cu(C2O4)2(H2O)]·2H2O, crystallizes in the space group P. In the solid state, the [Cu(ox)2(H2O)]2- units (ox is oxalate, C2O4) dimerize to give a tetragonally distorted CuO6 coordination environment. Extensive hydrogen bonding between the oxalate, the coordinated water, the 1,4-diazoniabicyclo[2.2.2]octane dications ([dabcoH2]2+) and the water of crystallization determines the crystal packing.

• Item Type: Articles
• Status: Published
• Refereed: Yes
• Glasgow Author(s) Enlighten ID: Price, Dr Daniel
• Authors: Keene, T.D., Hursthouse, M.B., and Price, D.J.
• College/School: College of Science and Engineering > School of Chemistry
• Journal Name: Acta Crystallographica. Section E: Structure Reports Online
• Publisher: International Union of Crystallography
• ISSN: 1600-5368
• ISSN (Online): 1600-5368
• Copyright Holders: Copyright © 2004 International Union of Crystallography
• First Published: First published in Acta Crystallographica. Section E: Structure Reports Online 60(4):M378-M380
• Publisher Policy: Reproduced in accordance with the copyright policy of the publisher