Structural and compositional control in {M-12} cobalt and nickel coordination clusters detected magnetochemically and with cryospray mass spectrometry

Cooper, G.J.T. , Newton, G.N., Kogerler, P., Long, D.L. , Engelhardt, L., Luban, M. and Cronin, L. (2007) Structural and compositional control in {M-12} cobalt and nickel coordination clusters detected magnetochemically and with cryospray mass spectrometry. Angewandte Chemie (International Edition), 46(8), pp. 1340-1344. (doi:10.1002/anie.200603870)

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Abstract

Control, but not a freak: A series of dodecanuclear coordination clusters of NiII and CoII with isostructural frameworks is prepared with unparalleled structural and compositional control. At different pH values, the respective clusters can be detected in solution by cryospray mass spectrometry. The positions of the metal centers in the mixed-metal clusters are determined from the magnetic properties.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Long, Dr Deliang and Cooper, Dr Geoff and Cronin, Professor Lee
Authors: Cooper, G.J.T., Newton, G.N., Kogerler, P., Long, D.L., Engelhardt, L., Luban, M., and Cronin, L.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Angewandte Chemie (International Edition)
Journal Abbr.:Angew Chem Int Ed Engl
Publisher:Wiley - V C H Verlag GmbH & Co. KGaA
ISSN:1433-7851
ISSN (Online):1521-3773
Published Online:29 January 2007

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Project CodeAward NoProject NamePrincipal InvestigatorFunder's NameFunder RefLead Dept
397491Adventurous research in chemistry: from proteins to surfaces (pushing the limits of powder diffraction; towards protein crystallography on a laboratory powder diffractometer)C GilmoreEngineering & Physical Sciences Research Council (EPSRC)EP/C532236/1Chemistry