Lee, M.R. and Lindgren, P. (2016) Aqueous alteration of chondrules from the Murchison CM carbonaceous chondrite: replacement, pore filling and the genesis of polyhedral serpentine. Meteoritics and Planetary Science, 51(6), pp. 1003-1021. (doi: 10.1111/maps.12644)
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Abstract
Forsterite and clinoenstatite in type IAB chondrules from the Murchison CM carbonaceous chondrite have been partially serpentinized, and the mechanisms of their alteration reveal crystallographic and microstructural controls on the reaction of silicate minerals with parent body aqueous solutions. Grains of forsterite were altered in two stages. Narrow veinlets of Fe-rich serpentine formed first and by the filling of sheet pores. Most of these pores were oriented parallel to (010) and (001) and had been produced by earlier fracturing and/or congruent dissolution. In the second stage, the subset of veinlets that were oriented parallel to (001) was widened accompanying the replacement of forsterite by Mg-Fe serpentine. This reaction proceeded most rapidly parallel to [001], and crystallographic controls on the trajectory of retreating vein walls created fine-scale serrations. Murchison clinoenstatite grains have a skeletal appearance due to the presence of abundant veinlets and patches of phyllosilicate. Two alteration stages can again be recognized, with initial water–mineral interaction producing tochilinite-rich veinlets by the filling of (001)-parallel contraction cracks. Pores then formed by congruent dissolution that was guided principally by orthopyroxene lamellae, and they were subsequently filled by submicrometer-sized crystals of polyhedral serpentine. This finding that Murchison forsterite and clinoenstatite grains have been altered demonstrates that aqueous processing of magnesium silicate minerals started much earlier in CM parent body history than previously believed. Our results also show that the occurrence of polyhedral serpentine can be used to locate former pore spaces within the parent body.
| Item Type: | Articles |
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| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Lee, Professor Martin and Lindgren, Dr Paula |
| Authors: | Lee, M.R., and Lindgren, P. |
| College/School: | College of Science and Engineering > School of Geographical and Earth Sciences College of Science and Engineering > Scottish Universities Environmental Research Centre |
| Journal Name: | Meteoritics and Planetary Science |
| Publisher: | Wiley |
| ISSN: | 1086-9379 |
| ISSN (Online): | 1945-5100 |
| Published Online: | 17 April 2016 |
| Copyright Holders: | Copyright © 2016 The Authors |
| First Published: | First published in Meteoritics and Planetary Science 51(6):1003-1021 |
| Publisher Policy: | Reproduced under a Creative Commons License |
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