Synthesis, bonding, and reactivity of vanadium(IV) oxido–fluorido compounds with neutral chelate ligands of the general formula cis-[VIV(═O)(F)(LN–N)2]+

Passadis, S. S., Tsiafoulis, C., Drouza, C., Tsipis, A. C., Miras, H. N. , Keramidas, A. D. and Kabanos, T. A. (2016) Synthesis, bonding, and reactivity of vanadium(IV) oxido–fluorido compounds with neutral chelate ligands of the general formula cis-[VIV(═O)(F)(LN–N)2]+. Inorganic Chemistry, 55(4), pp. 1364-1366. (doi: 10.1021/acs.inorgchem.5b02895) (PMID:26794835)

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Abstract

Reaction of the oxidovanadium(IV)−LN−N species (LN−N is bipy = 2,2′-bipyridine or bipy-like molecules) with a fluoride source (BF4-, HF, MF) afforded the compounds cis-[VIV(═O)(F)(LN−N)2]A (A = BF4−, ClO4−, SbF6−). Structural and spectroscopic characterization and density functional theory have been used to characterize these compounds, and their ability to act as efficient fluorinating agents was demonstrated.

Item Type:Articles
Additional Information:Funding: The authors gratefully acknowledge for the support the Greek Community Support FrameworkIII (MIS91629) and the Research Promotional Foundation of Cyprus and the European Structural Funds (ANABAΘMIΣH/ΠAΓIO/0308/32, YΓEIA/BIOΣ/ 0308(BIE)/13).
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Moiras, Professor Haralampos
Authors: Passadis, S. S., Tsiafoulis, C., Drouza, C., Tsipis, A. C., Miras, H. N., Keramidas, A. D., and Kabanos, T. A.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Inorganic Chemistry
Publisher:American Chemical Society
ISSN:0020-1669
ISSN (Online):1520-510X
Published Online:21 January 2016
Copyright Holders:Copyright © 2016 American Chemical Society
First Published:First published in Inorganic Chemistry 55(4):1364-1366
Publisher Policy:Reproduced in accordance with the copyright policy of the publisher.

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Project CodeAward NoProject NamePrincipal InvestigatorFunder's NameFunder RefLead Dept
MIS91