Postsynthetic bromination of UiO-66 analogues: altering linker flexibility and mechanical compliance

Marshall, R. J., Richards, T., Hobday, C. L., Murphie, C. F., Wilson, C. , Moggach, S. A., Bennett, T. D. and Forgan, R. S. (2016) Postsynthetic bromination of UiO-66 analogues: altering linker flexibility and mechanical compliance. Dalton Transactions, 45(10), pp. 4132-4135. (doi:10.1039/C5DT03178H) (PMID:26583777)

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Abstract

A new member of the UiO-66 series of zirconium metal-organic frameworks (MOFs) is reported, and the postsynthetic bromination of its integral alkene moeities in a single-crystal to single-crystal manner is fully characterised. Nanoindentation is used to show bromination of unsaturated carbon-carbon bonds in it and an analogous Zr MOF leads to more compliant materials with lower elastic moduli.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Wilson, Dr Claire and Forgan, Dr Ross and Marshall, Mr Ross James
Authors: Marshall, R. J., Richards, T., Hobday, C. L., Murphie, C. F., Wilson, C., Moggach, S. A., Bennett, T. D., and Forgan, R. S.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Dalton Transactions
Publisher:Royal Society of Chemistry
ISSN:1477-9226
ISSN (Online):1477-9234
Published Online:11 November 2015
Copyright Holders:Copyright © 2016 Royal Society of Chemistry
First Published:First published in Dalton Transactions 45(10): 4132-4135
Publisher Policy:Reproduced under a Creative Commons License
Data DOI:10.5525/gla.researchdata.231

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Project CodeAward NoProject NamePrincipal InvestigatorFunder's NameFunder RefLead Dept
619471Biomimetic guest selective metal-organic frameworks: catalysis and self-assemblyRoss ForganEngineering & Physical Sciences Research Council (EPSRC)EP/L004461/1CHEM - CHEMISTRY