Craig, G. A., Woodall, C. H., Campbell McKellar, S. C., Probert, M. R., Kamenev, K. V., Moggach, S. A., Brechin, E. K., Parsons, S. and Murrie, M. (2015) A high-pressure crystallographic and magnetic study of Na5[Mn(L-tart)2]•12H2O (L-tart = L-tartrate). Dalton Transactions, 44(42), pp. 18324-18328. (doi: 10.1039/C5DT03320A) (PMID:26447366)
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Abstract
The crystal structure and magnetic properties of the compound Na5[Mn(L-tart)2]•12H2O (1, L-tart = L-tartrate) have been investigated over the pressure range 0.34 – 3.49 GPa. The bulk modulus of 1 has been determined as 23.9(6) GPa, with a compression of the coordination spheres around the Na+ ions observed. 1 is therefore relatively incompressible, helping it to retain its magnetic anisotropy under pressure.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Craig, Dr Gavin and Murrie, Professor Mark |
Authors: | Craig, G. A., Woodall, C. H., Campbell McKellar, S. C., Probert, M. R., Kamenev, K. V., Moggach, S. A., Brechin, E. K., Parsons, S., and Murrie, M. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Dalton Transactions |
Publisher: | Royal Society of Chemistry |
ISSN: | 1477-9226 |
ISSN (Online): | 1477-9234 |
Published Online: | 30 September 2015 |
Copyright Holders: | Copyright © 2015 The Royal Society of Chemistry |
First Published: | First published in Dalton Transactions 44(42):18324-18328 |
Publisher Policy: | Reproduced under a Creative Commons License |
Data DOI: | 10.5525/gla.researchdata.209 |
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