Benelli, C., Murrie, M. , Parsons, S. and Winpenny, R. E.P. (1999) Synthesis, structural and magnetic characterisation of a new Mn–Gd pivalate: preparation from a pre-formed hexanuclear cluster. Dalton Transactions, 1999(23), pp. 4125-4126. (doi: 10.1039/A907977G)
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Abstract
The synthesis and crystal structures of two isostructural Mn(III)Ln(III) pivalates (Ln = Gd, Dy) are reported; magnetic data are presented for [Mn2Gd2O2(O2CCMe3)8(HO2CCMe3)2(MeOH)2], the susceptibility behaviour being dominated by strong antiferromagnetic coupling between the di-µ-oxo-bridged Mn(III) centres; this complex represents the first reported example of ferromagnetic coupling between Mn and Gd in a discrete polynuclear complex.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Murrie, Professor Mark |
| Authors: | Benelli, C., Murrie, M., Parsons, S., and Winpenny, R. E.P. |
| Subjects: | Q Science > QD Chemistry |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Dalton Transactions |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1477-9226 |
| ISSN (Online): | 1477-9234 |
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