Synthesis, structural and magnetic characterisation of a new Mn–Gd pivalate: preparation from a pre-formed hexanuclear cluster

Benelli, C., Murrie, M. , Parsons, S. and Winpenny, R. E.P. (1999) Synthesis, structural and magnetic characterisation of a new Mn–Gd pivalate: preparation from a pre-formed hexanuclear cluster. Dalton Transactions, 1999(23), pp. 4125-4126. (doi:10.1039/A907977G)

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Abstract

The synthesis and crystal structures of two isostructural Mn(III)Ln(III) pivalates (Ln = Gd, Dy) are reported; magnetic data are presented for [Mn2Gd2O2(O2CCMe3)8(HO2CCMe3)2(MeOH)2], the susceptibility behaviour being dominated by strong antiferromagnetic coupling between the di-µ-oxo-bridged Mn(III) centres; this complex represents the first reported example of ferromagnetic coupling between Mn and Gd in a discrete polynuclear complex.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Murrie, Professor Mark
Authors: Benelli, C., Murrie, M., Parsons, S., and Winpenny, R. E.P.
Subjects:Q Science > QD Chemistry
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Dalton Transactions
Publisher:Royal Society of Chemistry
ISSN:1477-9226
ISSN (Online):1477-9234

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