Leblanc, N., Sproules, S. , Pasquier, C., Auban-Senzier, P., Raffy, H. and Powell, A. K. (2015) Approaching the limit of CuII/CuImixed valency in a CuIBr2–N-methylquinoxalinium hybrid compound. Chemical Communications, 51(64), pp. 12740-12743. (doi: 10.1039/C5CC04142B)
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Abstract
A novel 1D hybrid salt (MQ)[CuBr2]∞ (MQ = N-methylquinoxalinium) is reported. Structural, spectroscopic and magnetic investigations reveal a minimal CuII doping of less than 0.1%. However it is not possible to distinguish CuI and CuII. The unusually close packing of the organic moieties and the dark brown colour of the crystals suggest a defect electronic structure.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Sproules, Dr Stephen |
| Authors: | Leblanc, N., Sproules, S., Pasquier, C., Auban-Senzier, P., Raffy, H., and Powell, A. K. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Chemical Communications |
| Journal Abbr.: | Chem. Comm. |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1359-7345 |
| ISSN (Online): | 1364-548X |
| Published Online: | 18 June 2015 |
| Copyright Holders: | Copyright © 2015 Royal Society of Chemistry |
| First Published: | First published in Chemical Communications 51(64):12740-12743 |
| Publisher Policy: | Reproduced in accordance with the copyright policy of the publisher |
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