Boyer, A. (2014) Rhodium(II)-catalyzed stereocontrolled synthesis of 2-tetrasubstituted saturated heterocycles from 1-Sulfonyl-1,2,3-triazoles. Organic Letters, 16(22), pp. 5878-5881. (doi: 10.1021/ol5028267)
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Abstract
Rhodium(II) acetate catalyzes the denitrogenative transformation of 4-substituted 1-sulfonyl-1,2,3-triazoles with pendent allyl and propargyl ethers and thioethers to onium ylides that undergo [2,3]-sigmatropic rearrangement to give 2-tetrasubstituted heterocycles with high yield and diastereoselectivity.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Boyer, Dr Alistair |
Authors: | Boyer, A. |
Subjects: | Q Science > QD Chemistry |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Organic Letters |
Publisher: | American Chemical Society |
ISSN: | 1523-7060 |
ISSN (Online): | 1523-7052 |
Copyright Holders: | Copyright © 2014 American Chemical Society |
First Published: | First published in Organic Letters 16(22):5878-5881 |
Publisher Policy: | Reproduced in accordance with the copyright policy of the publisher |
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