Rhodium(II)-catalyzed stereocontrolled synthesis of 2-tetrasubstituted saturated heterocycles from 1-Sulfonyl-1,2,3-triazoles

Boyer, A. (2014) Rhodium(II)-catalyzed stereocontrolled synthesis of 2-tetrasubstituted saturated heterocycles from 1-Sulfonyl-1,2,3-triazoles. Organic Letters, 16(22), pp. 5878-5881. (doi: 10.1021/ol5028267)

Abstract

Rhodium(II) acetate catalyzes the denitrogenative transformation of 4-substituted 1-sulfonyl-1,2,3-triazoles with pendent allyl and propargyl ethers and thioethers to onium ylides that undergo [2,3]-sigmatropic rearrangement to give 2-tetrasubstituted heterocycles with high yield and diastereoselectivity.

• Item Type: Articles
• Status: Published
• Refereed: Yes
• Glasgow Author(s) Enlighten ID: Boyer, Dr Alistair
• Authors: Boyer, A.
• Subjects: Q Science > QD Chemistry
• College/School: College of Science and Engineering > School of Chemistry
• Journal Name: Organic Letters
• Publisher: American Chemical Society
• ISSN: 1523-7060
• ISSN (Online): 1523-7052
• Copyright Holders: Copyright © 2014 American Chemical Society
• First Published: First published in Organic Letters 16(22):5878-5881
• Publisher Policy: Reproduced in accordance with the copyright policy of the publisher